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55. , Biochim. et Biophya. Acta 35,340 (1959). 56. Duysens, L. N. ,Science 121, 210 (1956). 34 MELVIN CALVIN 57. Kamen, M. , in “Light and fife” (W. D. McElroy and B. ), p. 436. Johns Hopkins Press, Baltimore, Maryland, 1961. 58. , Nature 175,803 (1955). 59. , in “Light and Life” (W. D. McElroy and B. ), p. 436. Johns Hopkins University Press, Baltimore, Maryland, 1961. 60. Duysens, L. N . , PTOC. Third Intern. Congr. , 1960 in press. 61. Witt, H. , Naturwissenachuften 42, 72 (1955);Witt, H. Chem.

V, Part 1, p. 884, Springer, Berlin, 1960. 4. Bassham, J. , and Calvin, M. ” W. A. , New York, 1962. 5. Bassham, J. , J. Chem. Educ. 86, 648 (1969); 38, 161 (1961); Soi. American June (1962). 6. Bassham, J. , Comp. Biochem. Phyeiol. 4, 187 (1962). , Science 135, 879 (1962). 7. van Niel, C. , in “The Microbe’s Contribution to Biology” (A. J. Kluyver and C. B. ), p. 155. Harvard Univ. Press, Cambridge, Massachusetts, 1966. 8. Amon, D. , Nature 184, 10 (1959). 9. Arnon, D. I. i n “Light and Life” (W.

This phenomenon was further studied by Rienacker and Hansen (3), and by Rienicker and Volter (30). On copper sheets, silver powder and iron powder, the decomposition was always perfectly zero-order, but on nickel “inhibited zero-order kinetics” were found (see Fig. 3), and the A D 61 (mm Hg) t =- 4- P ~ = 3 . 6rnrn 0 Hg 32- P ~ = l 6 0 m r nHg 1I 10 20 30 --. 3. Pressure increase aa a function of time in the static decomposition of formic acid on Ni-films at 190°C with different initial pressures P, [according to Rienacker and Hansen (3)].

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